Artificial photosynthesis uses sunlight to make biodegradable plastic

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In recent years, environmental problems caused by global warming have become more apparent due to greenhouse gases such as CO₂. In natural photosynthesis, CO₂ is not reduced directly, but is bound to organic compounds which are converted to glucose or starch. Mimicking this, artificial photosynthesis could reduce CO₂ by combining it into organic compounds to be used as raw materials, which can be converted into durable forms such as plastic.

A research team led by Professor Yutaka Amao from the Research Center for Artificial Photosynthesis and graduate student Mika Takeuchi, from the Osaka Metropolitan University Graduate School of Science, have succeeded in synthesizing fumaric acid from CO₂, a raw material for plastics, powered -- for the first time -- by sunlight. Their findings were published in Sustainable Energy & Fuels.

Fumaric acid is typically synthesized from petroleum, to be used as a raw material for making biodegradable plastics such as polybutylene succinate, but this discovery shows that fumaric acid can be synthesized from CO₂ and biomass-derived compounds using renewable solar energy.

"Toward the practical application of artificial photosynthesis, this research has succeeded in using visible light -- renewable energy -- as the power source," explained Professor Amao. "In the future, we aim to collect gaseous CO₂ and use it to synthesize fumaric acid directly through artificial photosynthesis."

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